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Autocatalytic Plating

Autocatalytic plating is a chemical process in which a uniform metal coating is deposited without an electric current.

What is Autocatalytic Plating?

Autocatalytic plating, also known as electroless plating, is a chemical process in which a metal coating is deposited on a surface without the use of electric current. Unlike electrolytic plating, which relies on an external power source, autocatalytic plating uses a chemical reaction that initiates the deposition of metal from a solution. This process provides a uniform coating even on complex geometries, internal surfaces or fine components. Autocatalytic plating is widely used in industries where precision, corrosion resistance and conductivity are essential, such as electronics, medical devices and the aerospace industry.

Autocatalytic Plating

The process of autocatalytic plating is driven by an autocatalytic chemical reaction. A reducing agent in the solution donates electrons, reducing metal ions and depositing them on the substrate surface. Because this deposition is not affected by electric field variations, a uniform coating is created. Common materials used in autocatalytic plating are nickel and copper, although alloys such as nickel-phosphorus or nickel-boron are often used to enhance specific properties. The process involves steps such as surface preparation, activation and then immersion in the autocatalytic solution, with deposition occurring gradually and achieving uniform thickness even in hard-to-reach areas.

Different Variants of Autocatalytic Plating

Several variants of autocatalytic plating exist, each tailored to specific performance requirements. For example, nickel-phosphorus plating is a common variant, where the phosphorus content (low, medium or high) can be adjusted to affect the hardness and corrosion resistance of the coating. Low-phosphorus coatings (1-4% P) offer excellent wear resistance and are ideal for industrial applications with high friction loads. High-phosphorus coatings (10-12% P), on the other hand, provide superior corrosion resistance, especially in aggressive chemical environments. Another variant is nickel-boron plating, which offers higher hardness and wear resistance than phosphorus-based coatings, making it suitable for applications requiring extreme durability. These variants allow for customization in coating performance depending on the final use.

Material suitability

Autocatalytic plating can be applied to a wide range of substrates, including metals, plastics and composites, provided the surface is properly prepared. Metals such as steel, aluminum and copper alloys are well suited for autocatalytic nickel plating. The key to optimal adhesion is thorough cleaning and activation of the substrate prior to plating. Non-metallic materials such as plastics require an additional step, usually an initial layer of autocatalytic copper, to create a conductive surface for further nickel deposition. Particular attention must be paid to surface activation, using catalysts such as palladium to ensure that the metal precipitates evenly on the substrate. Challenges such as uneven surface roughness or contamination can be avoided by our advanced pretreatment processes, resulting in a flawless coating.

Performance and Benefits

Autocatalytic plating offers several benefits, including increased wear resistance, corrosion resistance, electrical conductivity and improved hardness. For example, a nickel-phosphorus coating can significantly extend component life in harsh environments by providing up to 1,000 hours of salt spray resistance in high phosphorus variants. In addition, the uniform coating ensures consistent performance across all surfaces, even those with complicated geometries or hidden corners. This results in components that retain their structural integrity and appearance, reducing the need for frequent replacement or maintenance. The autocatalytic process also improves surface smoothness and precision, making it ideal for applications requiring precise tolerances.

Metal cylinders in different sizes in a rowApplications and Relevance in Industry

Autocatalytic plating is a highly versatile process used in a variety of industries, each benefiting from the specific properties of the coating. In electronics and telecommunications, it is often applied to circuit boards, connectors and other components where conductivity and corrosion resistance are critical. In medical devices, autocatalytic nickel coatings provide biocompatibility and protection against both corrosion and microbial contamination, making them suitable for surgical instruments and implants. In the aerospace industry, components with complex geometries, such as sensors and valve bodies, benefit from the uniform coating, which improves reliability and performance under harsh conditions. The ability of autocatalytic plating to meet strict industry standards, including MIL-C-26074 and AMS 2404 for aerospace, further emphasizes its relevance in critical applications.

Customization and Process Optimization

We offer extensive customization options for autocatalytic plating to meet our customers’ specific needs. For example, the thickness of the coating can be customized, from as thin as 5 microns to as much as 50 microns, depending on the desired properties. The phosphorus content can also be tuned to optimize for wear resistance or corrosion protection, allowing us to support a variety of industrial applications. In addition, our precise control over the plating process ensures consistent results in large production batches, so that each part receives the same high-quality finish. For customers with specific aesthetic or functional requirements, we offer additional finishing options, such as polishing or texturing.

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